Welcome to pond land! A quick question--with your aquarium experience have you used sump tanks? Ponds use very similar equipment--pumps, overflows, skimmers, bulkhead fittings, etc.
To combine 2 preformed liners, you have a couple options. You could turn one into a top pool of a waterfall that feeds into the second. This would have the benefit of good water aeration and movement, but it would have the downside of your fish being limited to one pool or the other (whichever one you choose to place them in). This could be a good thing if you wanted to separate the males and females.
You could also combine 2 liners by fitting a PVC pipe between the two. It would have to be large enough for your fish to travel through without risk of getting stuck, or debris clogging it up. This would give the benefit of creating two separate pools next to each other your fish could travel between "underground" which would be cool. They could also shelter in the tunnel if any predators showed up.
Both choices require some patience and can be tricky. With your first choice, you will need to cut the edge of one of the liners to create a waterfall spill way (or drill a hole for a pipe, to have the water spill from the pipe into the lower pool).
The second strategy you'll need to get bulkhead fittings to match the size of pipe you use. In case you're not aware, these are plastic fittings that thread through each of the holes you drill into the pond liner and create a water-tight seal.
The rule of thumb for ponds is that it should cycle at least half the pond's volume in the course of one hour. I personally prefer stronger filtration because it gets ridiculously hot where I live and oxygen levels in the water drop in the heat. So I make up for it by adding lots of aeration by cycling the water quickly.
Because your pond going to be relatively small, you could make a filter cheaply out of a 5 gallon bucket, bulkhead fittings, a few pieces of filtration foam, and some lava rock. You set up the pump to drain into the top of the 5 gallon bucket where you have your filter floss/foam to pick up big debris. The water travels down into the lava rock, which makes a great home for beneficial bacteria. At the bottom of the bucket, you have an outlet with a bulkhead fitting and pipe that feeds water back into the pond (preferably through a waterfall to add aeration.
There are lots of DIY videos on building your own filters on Youtube if that's something you're interested in. You can also buy filters that are designed for pumps. These work like canister filters, but often without an internal pump.
Good luck! I think your project is very exciting! I had tons of fun with my first pond, which was a 225 gallon preformed!