Shirley,I think you still need to get the pond bottom cleaned better so there is not so much gunk on the bottom. Can you invest in a net instead of a rake so it won't hurt the fish if it touches them? Anyways here's a bit about barley:
Maintaining a clean, clear pond is cheap and easy when you use barley straw. It helps control algae so your pond isn't covered over or muddied with these organisms. Plus, you'll feel good about using the barley straw because it won't harm the environment or plants, animals and fish that live in or around the pond. Barley straw is not an algaecide, so it doesn't kill algae. Instead, its decomposition creates an environment that is hostile to algae formation, leaving you with a cleaner pond.
Instructions
things you'll need:
4 to 8 ounces of barley straw
Mesh netting
Plastic soda bottle
Rope or heavy-duty string
1 -Purchase barley straw at your local garden supply store or online. Because it's commonly used to control algae in ponds, it's often sold already bundled in mesh. For a pond under 800 gallons, 4 ounces of barley straw is enough for each treatment. Ponds up to 1200 gallons will require 8 ounces of barley straw. Add 4 more ounces of barley straw for every 400 gallons over 1200.
2 -Wrap your barley straw securely in mesh netting if it isn't already. This allows the water to flow through the barley straw once you put it in the pond.
3 -Attach your bundle of barley straw to an empty soda bottle using rope or heavy duty string. The soda bottle will act as a float, preventing the barley straw bundle from settling into mud or muck at the bottom of your pond.
4 -Set the bundle in your pond in an area that gets good water circulation (near a waterfall or stream is ideal) and sunlight. If your pond is covered with algae, skim it off before setting the barley straw bundle. You'll achieve the best results if the barley straw receives sunlight (to aid the decomposition of the straw) and if water flows through it (distributing the resulting organic matter through the pond).
5 -Check the bundle after four months and add a new one if it's almost completely decomposed. Cooler northern climates will only require two treatments (one in early spring and one in late summer). Warmer southern climates may need treatment every four to six months.
Tips & Warnings
Expect to see results in about a month for barley straw treatments added when the pond is 40 degrees or less. Once the pond warms up, barley straw treatments show results in about two weeks. If the clarity of your pond doesn't improve after a month, check to make sure your barley straw bundle is in a spot that will give it maximum sunlight exposure and water circulation.
If your pond is particularly muddy, it may take a few treatments to see good results because mud will slow down the distribution of the decomposing barley straw particles. Don't substitute hay or another straw for barley straw. They will most likely decompose too fast, which can be harmful to plants and fish in your pond.