The
concrete raising pH myth has unfortunately being around the web for many years. Very easy to test and dispel. Sealers, of any kind, are not needed other than to try and stop leaks.
Whether a pond
needs to be cleaned depends on who you ask. A ponder with a pond full of large show Koi will say absolutely. A person with a wildlife pond will say absolutely never because the muck adds a lot of life to the pond. Both views are correct. The difference is the Koi owner is putting pounds of food into the pond daily or weekly. The waste piles up faster than it can break down and that's a problem. These types of ponds not only have to be cleaned, they have to be cleaned daily or at least weekly. Which is why they invest in automatic cleaning systems.
In a pond with a small amount of food added has time to convert waste to muck (there is a difference), same process as a compost pile. Muck is still a decaying pile with all kinds of bad stuff, but the many insects that live in it and fish like Goldfish and Koi have adapted to living in such an environment. That is their preferred environment.
The question is what kind of pond you want. Most people want clear water. Muck doesn't really have anything to do with whether water is clear or not, in general. Many ponds with muck are clear, many aren't. Many spotless ponds aren't clear, many are clear. However, removing muck does give you more control. Muck cycles. Gases can collect in it and cause chunks to break off and float around for awhile. Tiny flecks of decomposed organic matter can suspend and make water less clear. Lots of other issues. So muck can cause less clear water from time to time.
If you choose to remove muck I think the choice to vacuum depends on the pond size. A simple net is easier in tiny ponds. For larger ponds vacuums can work very well whether you're looking for a spotless pond. A pond with lots of plants can be difficult to vacuum, or making spotless is difficult. If you're just trying to reduce the depth of muck every five years or so a swimming pool leaf rake is enough. Here's my web page on
vacuums.