Depends on where you live. We have a rain barrel and considered the same. Some posted here that we should consider what falls on the roof, into the gutters, and into the barrel before we use the barrel water. Aside from the leach from shingles etc, whatever comes down there is concentrated by routing a large roof surface of water down into the gutters. After we thought about that we realized that every week or two, for most of the pond season, we are cleaning heavy pollen off of our porch furniture, not to mention the dirt and dust from the busy road that runs near the end of our property. Even if it's not toxic, nature takes care of what falls onto the ground and across the small surface of the pond, but I can't imagine it's a good thing to concentrate it into the gutters, then a rain barrel, and then into the pond. I'd use it just for plants.