I find it funny that the small new fish are not experiencing anything but the older, larger fish are. This almost sounds like the new fish introduced some parasites or disease into your pond. I would think that if your pond was poisoned the smaller fish would be affected by the comtaminants quicker than the larger fish. You could try adding alitte sale to the pond. You want noniodized salt at an amount of 3kg per 1000 liters for 2 to 3 weeks. Do not go higher than these amounts in your pond. If you need to treat them for parasites or bacterial infections I would reamove them and put them in a quarantine tank. This will allow you to see that the treatment is working and also help identify anything external on the fish much easier. Also, if you are having PH swing problems you can put 5-10 grams of baking soda (sodium bicarbonate) per 1000 liters per day in your pond until you get the ph stable. A PH of 7.5 to 8.3 is best case. Scallop, oyster shells, aragonite, limestone and dolomite are great to help buffer PH.