you mean for your soil garden beds? In a pond, pea gravel acts as a substrate to both support plants and their roots as well as a lot of surface area for denitrifying bacteria. In a garden soil bed, mulch acts as a moisture trap as well as will decay and provide nutrients to the plants. It also deters weeds, for a while. So, not the same function.
I used to have small rocks as my garden top dressing and though you'd think it would deter weeds, in time, I found it didn't and then, removing the weeds was a lot harder than using mulch (which is what I have now, or just plain soil).
Was there a purpose to why you want to use pea gravel instead of mulch or vice versa?